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Fabrication of 20 nm half-pitch gratings by corrugation-directed self-assembly

Ho-Cheol Kim1, Charles T Rettner and Linnea Sundström

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The evolution of the scaling of modern semiconductor devices is governed by the ability to create scalable high-resolution patterns on substrates. Since it is becoming increasingly difficult and expensive to extend to smaller dimensions using optical lithography, there is a great deal of interest in alternative patterning methods. The self-assembly of block copolymers in thin films, which provides periodic patterns of 10–50 nm length scales, has been recognized as a promising candidate for such patterning. To be practical, however, this approach must provide control over the orientation and lateral placement of the microdomains. We report here our discovery of the controlled alignment of the lamellar microdomains of a block copolymer containing hybrid material using topographic pre-patterns on substrates. We find that this hybrid material forms lamellae with a half-pitch of approximately 20 nm perpendicular to the lines of a surface corrugation.


 
Corrections were made to figure 1 of this article on 7 May 2008. The corrected electronic version is identical to the print version.
PACS

81.16.Dn Self-assembly

81.16.Nd Nanolithography

81.05.Lg Polymers and plastics; rubber; synthetic and natural fibers; organometallic and organic materials

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 23 (11 June 2008)

Received 10 March 2008, in final form 25 March 2008

Published 6 May 2008



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