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In situ synthesis and photoluminescence of QD-CdS on silk fibroin fibers at room temperature

Huilan Su1,3, Jie Han1, Qun Dong1, Di Zhang1 and Qixin Guo2

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A convenient room-temperature bioinspired technique has been developed to synthesize hybrid nanocomposites consisting of well-dispersed CdS quantum dots (QD) and the substrate silk fibroin fibers (SFF). The biomaterial SFF provides both a supporting substrate and functional sites for the in situ generation of QD-CdS, which is supported by FTIR and PL measurements. The solid QD-CdS/SFF nanocomposites could be useful in photocatalyst, novel luminescence and photoelectron transfer devices. The QD-CdS/silk fibroin (SF) colloid, in which SF acts as both an inherent biocompatibilizer and an efficient passivator of trap sites on the QD-CdS surface, is also available for some potential applications in the biological fields. The bioinspired method and relevant ideas could extend to fabricating other functional hybrid materials.


PACS

81.07.Ta Quantum dots

78.55.Et II-VI semiconductors

81.16.-c Methods of nanofabrication and processing

78.67.Hc Quantum dots

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Nanoscale science and low-D systems

Dates

Issue 2 (16 January 2008)

Received 1 May 2007, in final form 30 September 2007

Published 6 December 2007



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