Ni silicides in the form of nanobelts and nanosheets were synthesized for the first time based on the chemical reaction of Ni substrate with SiHCl₃ under H₂ atmosphere at 900 °C. Their morphological, structural and compositional features were characterized in detail using scanning electron microscopy, transmission electron microscopy, electron diffraction, energy-dispersive x-ray spectroscopy and x-ray diffraction. It was found that the nanobelts, 120–180 nm in thickness and 1–5 µm in width, comprise a single Ni₃Si phase and the nanosheets 20–80 nm in thickness consist of Ni₃Si and Ni₃₁Si₁₂, which is influenced by the concentration ratio of SiHCl₃ to H₂. Moreover, the potential application of these Ni silicides in electrochemical energy storage was also investigated. The results indicate that the nanosheets have excellent electrochemical performance when used as anode material for high energy density lithium ion batteries: a reversible capacity of more than 540 mA h g⁻¹ can be maintained even for the 20th cycle in a standard Li⁺ half-cell.