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Virus-mediated FCC iron nanoparticle induced synthesis of uranium dioxide nanocrystals

Tao Ling1,2, Huimin Yu3, Zhongyao Shen3, Hui Wang1,2 and Jing Zhu1,2

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A reducing system involving M13 virus-mediated FCC Fe nanoparticles was employed to achieve uranium reduction and synthesize uranium dioxide nanocrystals. Here we show that metastable face-centered cubic (FCC) Fe nanoparticles were fabricated around the surface of the M13 virus during the specific adsorption of the virus towards Fe ions under a reduced environment. The FCC phase of these Fe nanoparticles was confirmed by careful TEM characterization. Moreover, this virus-mediated FCC Fe nanoparticle system successfully reduced contaminable U(VI) into UO2 crystals with diameters of 2–5 nm by a green and convenient route.


PACS

87.85.Qr Nanotechnologies-design

61.46.Df Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots)

61.46.Hk Nanocrystals

Subjects

Nanoscale science and low-D systems

Dates

Issue 11 (19 March 2008)

Received 18 October 2007, in final form 24 December 2007

Published 18 February 2008



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