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Characterization of nanometer-sized, mechanically exfoliated graphene on the H-passivated Si(100) surface using scanning tunneling microscopy

Kyle A Ritter1,2 and Joseph W Lyding1,3

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We have developed a method for depositing graphene monolayers and bilayers with minimum lateral dimensions of 2–10 nm by the mechanical exfoliation of graphite onto the Si(100)-2 × 1:H surface. Room temperature, ultrahigh vacuum tunneling spectroscopy measurements of nanometer-sized single layer graphene reveal a size-dependent energy gap ranging from 0.1 to 1 eV. Furthermore, the number of graphene layers can be directly determined from scanning tunneling microscopy topographic contours. This atomistic study provides an experimental basis for probing the electronic structure of nanometer-sized graphene which can assist the development of graphene-based nanoelectronics.


PACS

73.22.-f Electronic structure of nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals

81.07.-b Nanoscale materials and structures: fabrication and characterization

68.37.Ef Scanning tunneling microscopy (including chemistry induced with STM)

85.35.-p Nanoelectronic devices

Subjects

Electronics and devices

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 1 (9 January 2008)

Received 24 September 2007, in final form 31 October 2007

Published 29 November 2007



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