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Comparison of GaP and PH3 as dopant sources for STM-based device fabrication

Kuan Eng Johnson Goh1,2,3, L Oberbeck1,2, M J Butcher2, N J Curson1,2, F J Rueß1,2 and M Y Simmons1,2

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We present a comparative study of the use of a GaP solid source as an alternative to gaseous PH3 for controlled phosphorus δ-doping of lithographic patterns on H:Si(001) fabricated by scanning tunnelling microscopy (STM). Whilst our electrical studies show that P δ-doping of Si with the GaP solid source and gaseous PH3 result in essentially the same electrical characteristics, our STM studies reveal that P2 molecules from the GaP source exhibit a lower selectivity between bare Si(001) and H:Si(001) compared to PH3 molecules. We discuss the significance of our findings in the context of fabricating nanoscale P dopant devices in Si using STM-based lithography.


PACS

68.37.Ef Scanning tunneling microscopy (including chemistry induced with STM)

81.16.Nd Nanolithography

68.47.Fg Semiconductor surfaces

73.63.-b Electronic transport in nanoscale materials and structures

71.55.Cn Elemental semiconductors

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 6 (14 February 2007)

Received 10 November 2006, in final form 15 December 2006

Published 10 January 2007



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