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PbS/PbSe structures with core–shell type morphology synthesized from PbS nanocrystals

Dmitry S Koktysh1,2, James R McBride1, Sriram K Dixit2,3, L C Feldman2,3,4 and Sandra J Rosenthal1,2,4

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Colloidal PbS/PbSe nanostructures with core–shell type morphology have been synthesized for the first time using a simple chemical procedure where template PbS nanocrystals (NCs) were treated with Se solution in tributylphosphine at elevated temperature. The Se-coated PbS NCs were structurally and optically characterized by high resolution transmission electron microscopy (HRTEM), x-ray diffraction (XRD), Rutherford backscattering spectrometry (RBS) analysis, absorption and photoluminescence (PL) spectroscopy. Synthesized PbS/PbSe structures can be of particular importance in photovoltaic applications where fabrication of heterostructures with compositional modulation on the nanometer scale is essential.


PACS

81.16.Be Chemical synthesis methods

82.70.Dd Colloids

61.46.Hk Nanocrystals

78.67.Bf Nanocrystals and nanoparticles

78.55.Hx Other solid inorganic materials

Subjects

Soft matter, liquids and polymers

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 49 (12 December 2007)

Received 20 August 2007

Published 15 November 2007



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