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Superior capacitive property of RuO2 nanoparticles on carbon nanotubes incorporated with nitrogen

Wei-Chuan Fang1,4, Kuei-Hsien Chen2 and Li-Chyong Chen3

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Fast charging–discharging performances of well-dispersed RuO2 nanoparticles (NPs) on N-doped carbon nanotubes (CNTs) have been demonstrated. As regards the structural properties, the N 1s x-ray photoelectron spectroscopy spectrum shows two characteristic bonding peaks of N within CNTs. Cross-sectional scanning electron microscope images show that N-doped CNTs provide good support for uniform distribution of RuO2 NPs. As regards the capacitive behavior, N-doped CNTs covered with well-dispersed RuO2 NPs lead to a high charging–discharging property performed at the scan rate of 2000 mV s−1. The role of N doping is to create preferential sites of CNTs for capturing RuO2 NPs. Such a fast sweep capability established by the N-incorporation method is very useful in supercapacitor applications.


PACS

82.45.Yz Nanostructured materials in electrochemistry

61.46.Fg Nanotubes

61.72.S- Impurities in crystals

79.60.Jv Interfaces; heterostructures; nanostructures

61.72.up Other materials

61.46.Df Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots)

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 48 (5 December 2007)

Received 22 August 2007, in final form 19 September 2007

Published 1 November 2007



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