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Structural and electronic properties of ZnO nanotubes from density functional calculations

Hu Xu1,2, R Q Zhang1,3,5, Xiaohong Zhang1, A L Rosa4 and Th Frauenheim4

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The structural and electronic properties of armchair and zigzag ZnO nanotubes were studied using density functional theory with the generalized gradient approximation. It was found that the strain energy required for rolling a ZnO graphitic sheet into a tube is lower than those for BN and GaN nanotubes. Both the armchair and zigzag ZnO nanotubes were found to be direct gap semiconductors with the gaps decreasing with the diameter increase.


PACS

61.46.Fg Nanotubes

73.22.-f Electronic structure of nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals

71.15.Mb Density functional theory, local density approximation, gradient and other corrections

Subjects

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 48 (5 December 2007)

Received 27 July 2007, in final form 26 September 2007

Published 1 November 2007



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