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Enhancing superplasticity of engineering ceramics by introducing BN nanotubes

Qing Huang1, Yoshio Bando1, Xin Xu2, Toshiyuki Nishimura1, Chunyi Zhi1, Chengchun Tang1, Fangfang Xu3, Lian Gao3 and Dmitri Golberg1

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Introducing carbon nanotubes (CNTs) into polymer or ceramic matrices has been a promising approach to obtain ultra-strong, extra-toughened materials as well as multifunctional composites. Most of the previous work on CNT composites has focused on strengthening and toughening of matrix materials at ambient conditions. However, so far there is a lack of information on the mechanical behavior of these composites at elevated temperature. Recently, single-walled CNTs were found to undergo a superplastic deformation with an appealing 280% elongation at a high temperature (Huang et al 2006 Nature 439 281). This discovery implies the high probability for the potential usage of CNTs as reinforcing agents in engineering high-temperature ceramics with improved ductility. Here, for the first time, we demonstrate that a small addition of boron nitride nanotubes (BNNTs) can dramatically enhance the high-temperature superplastic deformation (SPD) of engineering ceramics. More specifically, 0.5 wt% addition of BNNTs leads to an inspiring brittle-to-ductile transition in Al2O3 ceramics even at a moderate temperature (1300 °C). For Si3N4 ceramics, 0.5 wt% addition of BNNTs could also decrease the true stress by 75% under the same deformation conditions. In contrast, addition of micro-sized or nano-sized BN powders has no or a negative effect on the superplasticity of these ceramics. The underlying SPD-enhancement mechanism is discussed in terms of the inhibition of static and dynamic grain growth of the matrix and the energy-absorption mechanism of BNNTs. The unraveled capability of BNNTs to enhance the SPD behavior will make BNNTs promising components in cost-effective complex ceramics with good comprehensive mechanical properties.


PACS

81.40.Lm Deformation, plasticity, and creep

82.35.Np Nanoparticles in polymers

62.20.F- Deformation and plasticity

62.25.-g Mechanical properties of nanoscale systems

89.20.Kk Engineering

Subjects

Soft matter, liquids and polymers

Nanoscale science and low-D systems

Condensed matter: structural, mechanical & thermal

Chemical physics and physical chemistry

Dates

Issue 48 (5 December 2007)

Received 10 June 2007, in final form 1 October 2007

Published 30 October 2007



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