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Synthesis of high-quality near-infrared-emitting CdTeS alloyed quantum dots via the hydrothermal method

Weiyong Mao1,2, Jia Guo1,2, Wuli Yang1,2,5, Changchun Wang1,2, Jia He3,4 and Jiyao Chen3,4

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We present a facile one-pot method to fabricate water-dispersed near-infrared-emitting (650–800 nm) CdTeS alloyed quantum dots with high photoluminescence quantum yields (PL QYs). Due to the hydrolysis of thiol ligands, the sulfur was incorporated into the CdTe nanocrystals, forming CdTeS alloyed QDs. The effects of the type of thiol ligands, ligand-to-Cd molar ratio, and precursor concentration on the QDs were investigated, and thus high-quality water-dispersed CdTeS alloyed QDs (PL QYs 68%) were prepared with a high efficiency via the hydrothermal method. Water-dispersed CdTeS alloyed QDs with excellent emissions in the near-IR spectrum window have great potential in biological and medical applications especially in in vivo imaging.


PACS

81.07.Ta Quantum dots

81.16.-c Methods of nanofabrication and processing

78.67.Hc Quantum dots

78.55.Et II-VI semiconductors

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Nanoscale science and low-D systems

Dates

Issue 48 (5 December 2007)

Received 11 July 2007, in final form 7 September 2007

Published 1 November 2007



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