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Template electrosynthesis of CeO2 nanotubes

Rosalinda Inguanta, Salvatore Piazza and Carmelo Sunseri

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Nanotube arrays of CeO2 were produced in a single step by potentiostatic electrochemical deposition from a non-aqueous electrolyte, using anodic alumina membrane templates. The CeO2 nanotubes showed a polycrystalline structure, and they were assembled in the membrane nanochannels. The nanotubes had somewhat uniform diameters, with an average external value of about 210 nm, and a maximum length of about 60 µm; the latter parameter was controlled by the electrodeposition time. Each single nanotube was found to consist of crystalline grains having a size of about 3 nm. Raman analysis shows that these CeO2 nanotubes are suitable for catalytic applications.


PACS

61.46.Fg Nanotubes

82.45.Qr Electrodeposition and electrodissolution

81.07.De Nanotubes

Subjects

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 48 (5 December 2007)

Received 6 August 2007, in final form 9 October 2007

Published 1 November 2007



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