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Length-dependent thermal conductivity of single-wall carbon nanotubes: prediction and measurements

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ZhaoLiang Wang1, DaWei Tang1, XingHua Zheng1, WeiGang Zhang2 and YunTian Zhu3

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In this paper, we propose a modified wavevector (WV) model that takes account of the N-process relaxation time and second-order three-phonon process to predict the length dependence of the thermal conductivity of single-wall carbon nanotubes (SWNTs). The model is validated by length-dependent thermal conductivities of individual SWNTs measured using the four-pad 3ω method. The fitted Grüneisen parameter is close to 2 for SWNTs. These results indicate that the effect of the second-order three-phonon process cannot be neglected at room temperature. Both the experimental and theoretical results prove that the thermal conductivity increases with length of SWNTs over the range of 0.5–7 µm.


PACS

66.70.-f Nonelectronic thermal conduction and heat-pulse propagation in solids; thermal waves

63.22.-m Phonons or vibrational states in low-dimensional structures and nanoscale materials

61.46.Fg Nanotubes

Subjects

Nanoscale science and low-D systems

Condensed matter: structural, mechanical & thermal

Dates

Issue 47 (28 November 2007)

Received 31 July 2007, in final form 14 September 2007

Published 19 October 2007



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