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Growth mechanism and optical properties of ZnS nanotetrapods

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Zhanqiang Deng1, Junjie Qi1, Yue Zhang1,2,3, Qingliang Liao1 and Yunhua Huang1

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ZnS nanotetrapods have been synthesized through the direct reaction of Zn with S via a thermal evaporation method in Ar at 800 °C without catalyst. Studies on the microstructures give experimental evidence for the growth mechanism of ZnS nanotetrapods. A zinc blende (ZB) ZnS core nucleates in the first stage during the formation of ZnS nanotetrapods; wurtzite twins based on the ZB core then form and lead to the assembly of ZnS nanotetrapod structures. Room-temperature photoluminescence properties were also examined, showing a strong green emission centered at 495.2 nm.


PACS

81.16.-c Methods of nanofabrication and processing

78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures

81.07.-b Nanoscale materials and structures: fabrication and characterization

78.55.Et II-VI semiconductors

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Nanoscale science and low-D systems

Dates

Issue 47 (28 November 2007)

Received 3 September 2007, in final form 26 September 2007

Published 19 October 2007



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