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Synthesis of Ba-doped CeO2 nanowires and their application as humidity sensors

Zuwei Zhang1, Chenguo Hu1,4, Yufeng Xiong2, Rusen Yang3 and Zhong Lin Wang3

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Ba-doped CeO2 nanowires were obtained from CeO2 particles through a facile composite-hydroxide-mediated (CHM) route. The products were characterized by x-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and high-resolution transmission electron microscope (HRTEM). The formation process of the product was discussed. Humidity sensors based on the source material CeO2 particles, Ba-doped CeO2 nanowires grown for 12 and 72 h, were fabricated. The responses to humidity for static and dynamic testing proved that both doping Ba into CeO2 and converting morphology into a nanowire can improve the humidity sensitivity. The resistance changes from 465 to 3.9 MΩ as the relative humidity (RH) increases from 25% to 88%, indicating promising applications of Ba-doped CeO2 nanowires in environmental monitoring.


PACS

81.16.-c Methods of nanofabrication and processing

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

61.05.cp X-ray diffraction

07.07.Df Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing

68.37.Lp Transmission electron microscopy (TEM)

Subjects

Instrumentation and measurement

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 46 (21 November 2007)

Received 8 August 2007, in final form 18 September 2007

Published 12 October 2007



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