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The extraordinary reinforcing efficiency of single-walled carbon nanotubes in oriented poly(vinyl alcohol) tapes

Z Wang1, P Ciselli1,2 and T Peijs1,2

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This paper reports on oriented poly(vinyl alcohol)/single-walled carbon nanotube (PVA/SWNT) tapes that were prepared by a mild processing route, involving the use of dimethyl sulfoxide (DMSO) as a solvent. Composite films with homogeneously dispersed SWNTs were cast from solution and drawn into oriented tapes using solid-state drawing. The obtained tapes showed the extraordinary reinforcing effects of the SWNTs, as the addition of 1.0 wt% SWNTs tripled the tensile strength of the PVA tapes. Micromechanical analysis showed that the nanotube contribution to the composite strength was as high as 88 GPa, which is very high when compared to other data reported in the literature, and for the first time begins to exploit the theoretical strength of nanotubes.


PACS

61.46.Fg Nanotubes

62.20.F- Deformation and plasticity

81.40.Lm Deformation, plasticity, and creep

62.25.-g Mechanical properties of nanoscale systems

61.41.+e Polymers, elastomers, and plastics

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 45 (14 November 2007)

Received 6 July 2007, in final form 17 August 2007

Published 10 October 2007



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