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Wavelength-tunable lasing in single-crystal CdS1−XSeX nanoribbons

Y K Liu1, J A Zapien, Y Y Shan, H Tang, C S Lee and S T Lee2

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Alloyed ternary CdS1−XSeX nanoribbons of variable composition X were synthesized by the combination of thermal evaporation and laser ablation. High-resolution transmission electron microscopy and x-ray diffraction showed that the ternary CdS1−XSeX nanoribbons were single phase and highly crystalline. Room-temperature optical measurements showed that band-gap engineering could be realized in CdS1−XSeX nanoribbons via modulation in composition X. Lasing emission between the band-gap energy of CdS (512 nm) and that of CdSe (710 nm) was observed for composition 0<X<1 under optical pumping (266 nm) at power densities of 35–60 kW cm−2. Cathodoluminescence imaging and spectroscopy of single CdS1−XSeX nanoribbons reveal the uniform optical properties of the nanoribbons, which supports the absence of phase segregation within the nanoribbon. Fine tuning of the lasing wavelength via composition changes is shown to be smaller than 0.1 nm, and is capable of overlapping thermally induced tuning, demonstrating the possibility of continuous tuning in the lasing wavelength. The broad and fine tunable lasing properties of ternary nanoribbons have potential applications in color-tuned nanolasers, biological labels, and nano-optoelectronics.


PACS

81.16.-c Methods of nanofabrication and processing

78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures

79.70.+q Field emission, ionization, evaporation, and desorption

78.60.Hk Cathodoluminescence, ionoluminescence

68.37.Lp Transmission electron microscopy (TEM)

61.05.cp X-ray diffraction

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 36 (12 September 2007)

Received 4 May 2007, in final form 5 July 2007

Published 14 August 2007



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