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Laser-induced assembly of gold nanoparticles into colloidal crystals

N Harris, M J Ford, M B Cortie and A M McDonagh

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Micron-sized colloidal crystals comprised of gold nanospheres have been synthesized directly from a gold nanoparticle/methyl methacrylate colloid by application of a 514 nm laser at 500 mW. An array of colloidal crystals can be created by translation of the glass substrate under the laser beam, after 2 min of irradiation at each site. We demonstrate through a series of control experiments and calculations that plasmon-induced, localized heating of the gold nanoparticles contributes to the mechanism responsible for the formation of these colloidal crystals.


PACS

81.16.Mk Laser-assisted deposition

61.82.Rx Nanocrystalline materials

61.80.Ba Ultraviolet, visible, and infrared radiation effects (including laser radiation)

82.70.Dd Colloids

78.67.Bf Nanocrystals and nanoparticles

78.40.-q Absorption and reflection spectra: visible and ultraviolet

Subjects

Soft matter, liquids and polymers

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 36 (12 September 2007)

Received 5 June 2007

Published 10 August 2007



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