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A facile method to fabricate carbon-encapsulated Fe3O4 core/shell composites

Shouhu Xuan1,2, Lingyun Hao2,3, Wanquan Jiang2, Xinglong Gong3, Yuan Hu1,4 and Zuyao Chen2

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One-step synthesis of carbon-encapsulated Fe3O4 core/shell composites is reported. The Fe3O4 cores were formed via the reduction of Fe3+ by glucose under alkaline conditions obtained by the decomposition of urea. The amorphous carbon shells were carbonized from glucose. A possible formation mechanism for the Fe3O4@C composite was discussed. In order to characterize these Fe3O4@C core–shell composites, high-resolution transmission electron microscopy (HR-TEM), x-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), x-ray photoelectron spectroscopy (XPS) and a superconducting quantum interference device (SQUID) magnetometer were employed to characterize the sample obtained using the above method.


PACS

81.07.-b Nanoscale materials and structures: fabrication and characterization

68.37.Lp Transmission electron microscopy (TEM)

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

81.16.Be Chemical synthesis methods

79.60.Jv Interfaces; heterostructures; nanostructures

78.30.-j Infrared and Raman spectra

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 3 (24 January 2007)

Received 28 August 2006, in final form 6 November 2006

Published 3 January 2007



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