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Electronic and atomic shell structure in aluminium nanowires

A I Mares1, D F Urban2, J Bürki3, H Grabert2, C A Stafford3 and J M van Ruitenbeek1

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We report experiments on aluminium nanowires in ultra-high vacuum at room temperature that reveal a periodic spectrum of exceptionally stable structures. Two 'magic' series of stable structures are observed: at low conductance, the formation of stable nanowires is governed by electronic shell effects whereas for larger contacts atomic packing dominates. The crossover between the two regimes is found to be smooth. A detailed comparison of the experimental results to a theoretical stability analysis indicates that, while the main features of the observed electron-shell structure are similar to those of alkali and noble metals, a sequence of extremely stable wires plays a unique role in aluminium. This series appears isolated in conductance histograms and can be attributed to 'superdeformed' non-axisymmetric nanowires.


PACS

61.46.-w Structure of nanoscale materials

68.65.La Quantum wires (patterned in quantum wells)

73.22.-f Electronic structure of nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 26 (4 July 2007)

Received 22 March 2007, in final form 14 May 2007

Published 7 June 2007



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