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Step-edge like template fabrication of polyelectrolyte supported nickel nanowires

Devesh Srivastava, Troy R Hendricks and Ilsoon Lee1

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A method to produce novel polymer supported nickel nanowires, which are asymmetric (or anisotropic) in shape and function, using an alumina membrane as a template is presented. This paper reports a step-edge like fabrication technique using anodized alumina membranes. First the membrane is treated with fluorosilanes to make the surface completely hydrophobic. It is then cleaved to expose the freshly prepared alumina edges, which are hydrophilic. These freshly cleaved hydrophilic edges are used as templates for the deposition of polyelectrolyte multilayers and nickel. We selectively deposit polyelectrolyte multilayers on those hydrophilic edges. Then the electroless deposition of nickel is used to create nickel nanowires. After dissolving the membranes, we obtain nanostructures which are asymmetric in shape and function.


PACS

81.07.Vb Quantum wires

82.45.Mp Thin layers, films, monolayers, membranes

82.45.Aa Electrochemical synthesis

82.45.Qr Electrodeposition and electrodissolution

81.16.Be Chemical synthesis methods

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 24 (20 June 2007)

Received 15 March 2007, in final form 18 April 2007

Published 18 May 2007



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