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Structure analysis and optical study of In–O–N nanospears

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Baoyu Liu1, Xiyi Chen2 and Jinlei Yao3

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Novel spear-like In–O–N nanostructures have been synthesized on a Si substrate via a simple thermal evaporation process by ammoniating the In-containing reactants at 1100 °C. All the In–O–N nanostructures contain a long, thin pole with a diameter ranging from 20 to 100 nm and a huge spear-like tip at the end. The structure and morphology, as well as the crystallinity and composition of the In–O–N nanospears, were characterized by a scanning electron microscope (SEM), a transmission electron microscope (TEM) and the attached energy dispersive system (EDS). TEM analysis confirmed the cubic structure of In–O–N nanospears. Room-temperature cathodoluminescence (CL) measurement indicated that the In–O–N nanospears have a broad and strong light emission centred at ~454 nm with an unobvious shoulder in the range of 500–600 nm.


PACS

61.46.-w Structure of nanoscale materials

78.60.Hk Cathodoluminescence, ionoluminescence

68.37.Lp Transmission electron microscopy (TEM)

81.16.-c Methods of nanofabrication and processing

78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 19 (16 May 2007)

Received 4 January 2007, in final form 18 March 2007

Published 17 April 2007



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