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Sonochemical synthesis, structure and magnetic properties of air-stable Fe3O4/Au nanoparticles

Wei Wu1, Quanguo He1,3, Hong Chen1,2, Jianxin Tang1 and Libo Nie1

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Air-stable nanoparticles of Fe3O4/Au were prepared via sonolysis of a solution mixture of hydrogen tetrachloroaureate(III) trihydrate (HAuCl4) and (3-aminopropyl)triethoxysilane (APTES)-coated Fe3O4 nanoparticles with further drop-addition of sodium citrate. The Fe3O4/Au nanoparticles were characterized by x-ray powder diffraction (XRD), ultraviolet–visible spectroscopy (UV–vis), scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), x-ray photoelectron spectroscopy (XPS) and superconducting quantum interference device (SQUID) magnetometry. Nanoparticles of Fe3O4/Au obtained under appropriate conditions possess a very high saturation magnetization of about 63 emu g−1 and their average diameter is about 30 nm.


PACS

61.46.Df Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots)

81.16.Be Chemical synthesis methods

68.37.Lp Transmission electron microscopy (TEM)

68.37.Ef Scanning tunneling microscopy (including chemistry induced with STM)

61.05.cp X-ray diffraction

75.75.+a Magnetic properties of nanostructures

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 14 (11 April 2007)

Received 29 November 2006, in final form 22 January 2007

Published 6 March 2007



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