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PTCDA molecules on an InSb(001) surface studied with atomic force microscopy

J J Kolodziej, M Goryl, J Konior, F Krok and M Szymonski

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PTCDA (3,4,9,10-perylene-tetracarboxylic-dianhydride) molecular structures assembled on an InSb(001) c(8 × 2) reconstructed surface have been studied using frequency modulated atomic force microscopy. The high-resolution imaging of the structures is possible through repulsive interactions, using the constant height scanning mode. During initial stages of growth the [110] diffusion channel dominates as indicated by formation of long PTCDA molecular chains parallel to the [110] crystallographic direction on the InSb surface. For a single monolayer coverage a wetting layer of PTCDA is formed. Finally it is shown that the PTCDA/InSb is a promising system for building molecular nanostructures by manipulation of single molecules with the AFM tip.


PACS

68.37.Ps Atomic force microscopy (AFM)

68.35.B- Structure of clean surfaces (and surface reconstruction)

68.47.Fg Semiconductor surfaces

82.37.Gk STM and AFM manipulations of a single molecule

Subjects

Semiconductors

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 13 (4 April 2007)

Received 1 November 2006, in final form 4 January 2007

Published 28 February 2007



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