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Efficiently producing single-walled carbon nanotube rings and investigation of their field emission properties

Li Song1,5, Lijie Ci2, Chuanhong Jin1, Pingheng Tan3, Lianfeng Sun4, Wenjun Ma1, Lifeng Liu1, Dongfang Liu1, Zengxing Zhang1, Yanjuan Xiang1, Shudong Luo1, Xiaowei Zhao1, Jun Shen1, Jianjun Zhou1, Weiya Zhou1 and Sishen Xie1,6

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Single-walled carbon nanotube (SWNT) rings with a diameter of about 100 nm have been prepared by thermally decomposing hydrocarbon in a floating catalyst system. These rings appeared to consist mostly of SWNT toroids. High resolution transmission electron microscopy showed that these rings were composed of tens of SWNTs with a tightly packed arrangement. The production of SWNT rings was improved through optimizing various growth parameters, such as growth temperature, sublimation temperature of the catalyst, different gas flows and different catalyst components. The growth mechanism of the SWNT rings is discussed. In the field emission measurements we found that field emission from a halved ring is better than that from a whole SWNT ring, which contributed to the better emission from two opened ends of the nanotubes of the halved SWNT ring.


PACS

81.07.De Nanotubes

79.70.+q Field emission, ionization, evaporation, and desorption

81.16.Hc Catalytic methods

65.80.+n Thermal properties of small particles, nanocrystals, nanotubes

61.46.Fg Nanotubes

73.63.Fg Nanotubes

Subjects

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 9 (14 May 2006)

Received 17 December 2005

Published 11 April 2006



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