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Magnetoelectric coupling in ε-Fe2O3 nanoparticles

M Gich1, C Frontera1, A Roig1, J Fontcuberta1, E Molins1, N Bellido2, Ch Simon2 and C Fleta3

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Nanoparticles of the ferrimagnetic ε-Fe2O3 oxide have been synthesized by the sol–gel method. Here we report on the measurement of the dielectric permittivity as a function of temperature, frequency and magnetic field. It is found that, coinciding with the transition from collinear ferrimagnetic ordering to an incommensurate magnetic state occurring at about 100 K, there is an abrupt change (about 30%) of permittivity, suggesting the existence of magnetoelectric coupling in this material. Indeed, magnetic field-dependent measurements at 100 K have revealed an increase in the permittivity of about 0.3% in 6 T. Possible advantages of ε-Fe2O3 as a magnetoelectric material are discussed.


PACS

75.80.+q Magnetomechanical and magnetoelectric effects, magnetostriction

75.50.Tt Fine-particle systems; nanocrystalline materials

75.30.Kz Magnetic phase boundaries (including magnetic transitions, metamagnetism, etc.)

75.75.+a Magnetic properties of nanostructures

77.22.Ch Permittivity (dielectric function)

75.50.Gg Ferrimagnetics

Subjects

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 3 (14 February 2006)

Received 24 August 2005, in final form 24 November 2005

Published 6 January 2006



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