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Synthesis of uniform carbon@silica nanocables and luminescent silica nanotubes with well controlled inner diameters

Haisheng Qian1, Shu-Hong Yu1,3, Lei Ren2, Yipeng Yang1 and Wei Zhang1

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Uniform carbon@silica nanocables and silica nanotubes with well-controlled inner diameters can be synthesized in an easy way by a sacrificial templating method. This was performed using carbon nanofibres as hard templates that were synthesized previously by a hydrothermal carbonization process. Silica nanotubes with well-controlled inner diameters were synthesized from carbon@silica core–shell nanostructures by removal of the core carbon component. The inner diameters of the as-prepared silica nanotubes can be well controlled from several nanometres to hundreds of nanometres by adjusting the diameters of the carbon nanofibres. The silica nanotubes synthesized by this method display strong photoluminescence in ultraviolet at room temperature. Such uniform silica nanotubes might find potential applications in many fields such as encapsulation, catalysis, chemical/biological separation, and sensing.


PACS

81.07.De Nanotubes

81.16.Be Chemical synthesis methods

78.67.Ch Nanotubes

78.55.Hx Other solid inorganic materials

61.46.Fg Nanotubes

78.40.Ha Other nonmetallic inorganics

Subjects

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 24 (28 December 2006)

Received 5 August 2006, in final form 8 October 2006

Published 22 November 2006



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