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Fabrication of Fe3O4 nanoparticle arrays via patterned template assisted self-assembly

Tomoyuki Ogawa1,4, Yasuhiro Takahashi1, Haitao Yang1, Kaori Kimura2, Masatoshi Sakurai2 and Migaku Takahashi3

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Magnetic nanoparticle arrays have been fabricated by combining chemically synthesized Fe3O4 nanoparticles with a diblock copolymer template substrate consisting of self-assembled polystyrene (PS) dots in a polymethylmethacrylate (PMMA) matrix. The influence of the volume fraction of the Fe3O4 suspending solution and the withdrawal speed of the template on the formation of array structures was investigated. A small volume fraction of the nanoparticles and low withdrawal speed play an important role in the fabrication of the patterned arrays of nanoparticles via template assisted self-assembly. Below a withdrawal speed of 0.5 mm s−1 and a nanoparticle volume fraction below 0.05 vol% (in particular, at extremely high dilutions of less than 0.01 vol%), the selective deposition of one to several nanoparticles on every single PS dot becomes possible.


PACS

81.07.-b Nanoscale materials and structures: fabrication and characterization

75.75.+a Magnetic properties of nanostructures

78.30.-j Infrared and Raman spectra

81.16.Dn Self-assembly

Subjects

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 22 (28 November 2006)

Received 15 August 2006, in final form 30 September 2006

Published 25 October 2006



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