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Application of spectromicroscopy tools to explore local origins of sensor activity in quasi-1D oxide nanostructures

A Kolmakov1, U Lanke2, R Karam3, J Shin4, S Jesse4 and S V Kalinin4

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We have tested a range of imaging and spectroscopic techniques to address their ability to locally explore the interplay between surface reactivity and transport properties of the metal oxide nanostructure wired as a chemiresistor and chemi-FET. In particular, we used scanning surface potential microscopy (SSPM) to monitor the spatial and temporal particularities of the dc potential distributions in an operating device. We also successfully implemented synchrotron radiation-based photoelectron emission microscopy (PEEM) to explore submicron lateral compositional and electronic (work function) inhomogeneity on the surface of an individual nanowire sensor. These results open new avenues to visualize and spectroscopically address the chemical phenomena on an individual quasi-1D nanostructure both in real time and at nano- and mesoscopic level.


PACS

07.07.Df Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing

82.65.+r Surface and interface chemistry; heterogeneous catalysis at surfaces

81.07.-b Nanoscale materials and structures: fabrication and characterization

68.37.Xy Scanning Auger microscopy, photoelectron microscopy

85.35.-p Nanoelectronic devices

73.63.-b Electronic transport in nanoscale materials and structures

Subjects

Electronics and devices

Instrumentation and measurement

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 16 (28 August 2006)

Received 25 May 2006, in final form 23 June 2006

Published 14 July 2006



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