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Synthesis, characterization and field-emission properties of bamboo-like β-SiC nanowires

Guozhen Shen1, Yoshio Bando, Changhui Ye, Baodan Liu and Dmitri Golberg

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Single-crystalline bamboo-like β-SiC nanowires with hexagonal cross-sections were synthesized by thermal evaporation of mixed SiO+C+GaN powders in an Ar atmosphere. The as-synthesized nanowires were studied by x-ray diffraction, scanning electron microscopy and transmission electron microscopy. Studies found that the as-synthesized SiC nanowires are composed of hexagonal stems decorated with larger diameter knots along their whole length with the \langle 111\rangle
growth direction. The growth of bamboo-like SiC nanowires is governed by the vapour–liquid–solid mechanism. Field-emission properties of the peculiar nanostructures were also explored, showing a turn-on field of about 10.1 V µm−1.


PACS

81.07.Vb Quantum wires

81.16.Be Chemical synthesis methods

61.05.cp X-ray diffraction

61.46.-w Structure of nanoscale materials

79.70.+q Field emission, ionization, evaporation, and desorption

Subjects

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 14 (28 July 2006)

Received 15 March 2006, in final form 22 May 2006

Published 20 June 2006



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