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Room temperature synthesis of nano-carbons using an electrochemical technique of organic solution

H Yokomichi1, F Sakai2, M Ichihara2 and N Kishimoto3

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Room temperature synthesis of nano-carbons, i.e., whiskers, wires, onions and tubes, has been achieved by an electrochemical process under a liquid phase of organic solution with a metal catalyst. The electrochemical method supplies athermal energy to the reactants contrary to ordinary methods, i.e., this method creates nano-carbons directly transferring electrons at the electrode in the condensed phase, and the temperature does not increase during the synthesis. The nano-carbons with various structures were obtained by using C2H5OH with \mathrm {Ni}(\mathrm {NO}_{3})_{n}{\bdot }\mathrm {mH}_{2}\mathrm
{O} solution under a high electric field. The metal catalyst plays an important role in the nano-carbon growth in the present method, in a similar way to the usual methods. By virtue of the low temperature synthesis, this technique has great advantages in nano-scale interconnections and large area field emission cathodes of nano-carbons in next-generation devices on a thermally unstable substrate.


PACS

81.16.Be Chemical synthesis methods

82.45.Aa Electrochemical synthesis

Subjects

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 8 (August 2005)

Received 15 December 2004, in final form 22 March 2005

Published 20 May 2005



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