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Synthesis of photoconducting ZnO nano-needles using an unbalanced magnetron sputtered ZnO/Zn/ZnO multilayer structure

Sanjeev Kumar1, Vinay Gupta and K Sreenivas

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The synthesis of ZnO nano-needles using unbalanced magnetron sputtering is reported. A multilayer structure comprised of ZnO(50 nm)/Zn(20 nm)/ZnO(2 µm) was grown on a stainless steel substrate without substrate heating. The growth of ZnO nano-needles was observed on the surface of the multilayer structure after post-annealing treatment at 300–400 °C. The nano-needles were distributed randomly over the entire surface and had an average diameter of 20 nm; their length varied from 2 to 5 µm. The ultra-thin Zn layer (20 nm) in the multilayer structure is attributed to act as a nucleating centre and it activates the coalescence process for the growth of ZnO nano-needles. The ZnO nano-needles showed enhanced ultraviolet photoresponse with an initial fast rise and decay. The origin of the photoconductivity is due to the bulk related process. Results show the myriad application of ZnO nano-needles in ultraviolet light detection.


PACS

81.16.-c Methods of nanofabrication and processing

72.40.+w Photoconduction and photovoltaic effects

68.65.Ac Multilayers

81.40.Gh Other heat and thermomechanical treatments

81.07.Bc Nanocrystalline materials

79.20.Rf Atomic, molecular, and ion beam impact and interactions with surfaces

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 8 (August 2005)

Received 11 February 2005, in final form 22 April 2005

Published 17 May 2005



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