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Non-contact AFM study of the oxidized surface of single-crystalline SrTiO3 with porphyrin-based molecules

Shukichi Tanaka, Hitoshi Suzuki, Mitsuru Inada, Toshiya Kamikado and Shinro Mashiko

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The SrTiO3(100) surface as a substrate for supramolecular structuring was studied using frequency-modulated non-contact atomic force microscopy (FM-NCAFM). After appropriate etching and heating treatments, unit-cell steps with atomically flat and smooth surfaces were successfully obtained. These surfaces were found to be quite stable under UHV conditions as long as the temperature was kept below 600 K. Specially tailored porphyrin-based molecules were deposited on the substrates as a trial case to control their diffusion process on the substrate. Strong suppression of their mobility on the surface was found by FM-NCAFM observations.


PACS

68.37.Ps Atomic force microscopy (AFM)

66.30.-h Diffusion in solids

81.65.Cf Surface cleaning, etching, patterning

81.40.Gh Other heat and thermomechanical treatments

81.65.Mq Oxidation

Subjects

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Dates

Issue 3 (March 2005)

Received 21 October 2004, in final form 5 December 2004

Published 28 January 2005



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