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Selective-area MOVPE fabrication of GaAs hexagonal air-hole arrays on GaAs(111)B substrates using flow-rate modulation mode

Junichiro Takeda1, Masashi Akabori1,3, Junichi Motohisa1, Richard Nötzel2 and Takashi Fukui1

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GaAs hexagonal air-hole arrays fabricated by selective-area metal-organic vapour phase epitaxy (SA-MOVPE) on patterned GaAs(111)B substrates are promising for applications to hexagonal air-hole-type two-dimensional photonic crystal (2D-PhC) slabs, because the grown structures exhibit smooth flat surfaces surrounded by crystal facets. In this paper, we describe SA-MOVPE carried out under various gas-flow sequences in order to reduce the growth temperature, and to obtain uniform air-hole arrays without lateral over-growth (LOG). We found that the growth rate in the pattern region and LOG were closely related to the effective As coverage and the desorption rate of the source materials. By optimizing SA-MOVPE, we obtained uniform hexagonal air-hole arrays with almost no LOG for arrays with 500–400 nm periodicity using alternate supply of the source materials (flow-rate modulation epitaxy mode). Finally, we successfully fabricated air-bridge-type hole arrays using selective etching of a sacrificial layer for vertical confinement of light in 2D-PhCs.


PACS

81.15.Gh Chemical vapor deposition (including plasma-enhanced CVD, MOCVD, etc.)

68.47.Fg Semiconductor surfaces

42.70.Qs Photonic bandgap materials

81.15.Kk Vapor phase epitaxy; growth from vapor phase

68.43.Mn Adsorption kinetics

Subjects

Semiconductors

Surfaces, interfaces and thin films

Optics, quantum optics and lasers

Dates

Issue 12 (December 2005)

Received 24 August 2005, in final form 30 September 2005

Published 25 October 2005



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