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Growth of ZnO hexagonal nanoprisms

D F Liu, Y J Xiang, Z X Zhang, J X Wang, Y Gao, L Song, L F Liu, X Y Dou, X W Zhao, S D Luo, C Y Wang, W Y Zhou, G Wang and S S Xie1

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We show the success of large-scale growth of ZnO hexagonal nanoprisms on silicon substrates by a two-staged mechanism. In the first stage, the catalyst nanoparticles assisted the nucleation via the vapour–liquid–solid (VLS) mechanism to form polyhedral nanoparticles. In the second stage, the nanoprism was grown up by anisotropic homoepitaxy, layer by layer, on the c-face of the polyhedral nanoparticle. The surface of the nanoprism consists of the ultraflat {0001} and \{10\bar {1}0\} planes. The nanoprism is 200–500 nm in width and controllably sized in length, of high crystalline quality and excellent optical quality. This nanoprism would be an interesting building block for highly efficient nanolasers.


PACS

81.16.-c Methods of nanofabrication and processing

78.67.Bf Nanocrystals and nanoparticles

78.55.Et II-VI semiconductors

61.46.Df Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots)

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Nanoscale science and low-D systems

Dates

Issue 11 (November 2005)

Received 11 July 2005, in final form 26 August 2005

Published 30 September 2005



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