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Magnetic properties of ε-Fe3N–GaN core–shell nanowires

N S Gajbhiye1,2,3 and Sayan Bhattacharyya1

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ε-Fe3N–GaN core–shell nanowires are synthesized by the wet chemical route and by nitridation of the Fe–Ga-oxide nanowires in flowing NH3 (g). The encapsulation by the GaN shell protects the ε-Fe3N core and spin-glass-like cooperative ordering is observed at low temperatures. Magnetic disorder occurs at the ε-Fe3N–GaN interface, giving rise to the spin-glass-like state below 50 K because of the presence of anti-ferromagnetic (AF) mixed oxynitrides and ferromagnetic (FM) ε-Fe3N nitride and the random distribution of ε-Fe3N in the interface region. The spin-glass-like ordering is probed by relaxation and ac susceptibility experiments.


PACS

75.75.+a Magnetic properties of nanostructures

75.70.Cn Magnetic properties of interfaces (multilayers, superlattices, heterostructures)

61.46.-w Structure of nanoscale materials

81.16.Be Chemical synthesis methods

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 10 (October 2005)

Received 8 April 2005, in final form 5 June 2005

Published 3 August 2005



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