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Electron transport in semiconducting carbon nanotubes with hetero-metallic contacts

Yongqiang Xue1,3 and Mark A Ratner2

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We present an atomistic self-consistent study of the electronic and transport properties of semiconducting carbon nanotubes in contact with metal electrodes of different work functions, which shows simultaneous electron and hole doping inside the nanotube junction through contact-induced charge transfer. We find that the band lineup in the nanotube bulk region is determined by the effective work function difference between the nanotube channel and source/drain electrodes, while electron transmission through the SWNT junction is affected by the local band structure modulation at the two metal–nanotube interfaces, leading to an effective decoupling of interface and bulk effects in electron transport through nanotube junction devices.


PACS

73.63.Fg Nanotubes

73.30.+y Surface double layers, Schottky barriers, and work functions

73.40.Ns Metal-nonmetal contacts

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 1 (January 2005)

Received 4 October 2004, in final form 2 November 2004

Published 30 November 2004



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