Quick search Find article
Quick search
Find article

Biosensing based upon molecular confinement in metallic nanocavity arrays

Y Liu1, J Bishop1, L Williams2, S Blair1,2,4 and J Herron2,3

Show affiliations


We describe the basis for an affinity biosensor platform in which enhanced fluorescence transduction occurs through the optical excitation of molecules located within metallic nanocavities. These nanocavities are about 200 nm in diameter, are arranged in periodic or random two-dimensional arrays, and are fabricated in 70 nm thick gold films by e-beam lithography using negative e-beam resist. The experimental results show that both periodic and randomly placed metallic nanocavities can be used to enhance the fluorescence output of molecules within the cavities by about a factor of ten. In addition, the platform provides isolation from fluorescence produced by unbound species, making it suitable for real-time detection. Finally, we demonstrate the use of the platform in the real-time detection of 20-base oligonucleotides in solution.


PACS

87.85.Qr Nanotechnologies-design

87.15.M- Spectra of biomolecules

81.16.Nd Nanolithography

87.80.-y Biophysical techniques (research methods)

Subjects

Instrumentation and measurement

Medical physics

Biological physics

Nanoscale science and low-D systems

Dates

Issue 9 (September 2004)

Received 10 April 2004

Published 13 August 2004



  1. Biosensing based upon molecular confinement in metallic nanocavity arrays

    Y Liu et al 2004 Nanotechnology 15 1368

  2. 'Mind the gap': science and ethics in nanotechnology

    Anisa Mnyusiwalla et al 2003 Nanotechnology 14 R9

  3. Natural strategies for the molecular engineer

    Philip Ball 2002 Nanotechnology 13 R15

  4. Device to locate the centre of mass of a test object to within a precision of micrometres

    R S Davis 1995 Meas. Sci. Technol. 6 227

  5. Nitrogen contamination in elastic neutron scattering

    Songxue Chi et al 2011 Meas. Sci. Technol. 22 047001

  6. Modulation transfer spectroscopy in atomic rubidium

    D J McCarron et al 2008 Meas. Sci. Technol. 19 105601

  7. Magnetic direct generation of acoustic resonances in silicon membranes

    Frieder Lucklum et al 2006 Meas. Sci. Technol. 17 719

  8. The characterization of human compact bone structure changes by low-field nuclear magnetic resonance

    Qingwen Ni et al 2004 Meas. Sci. Technol. 15 58

  9. Generic reality visualization modelling from process tomography sensor data in process design

    B S Hoyle and X Jia 2004 Meas. Sci. Technol. 15 1355

  10. A field-programmable gate-array-based high-resolution pulse programmer

    S B Belmonte et al 2003 Meas. Sci. Technol. 14 N1

View by subject




Export








Please login to access our web services, or create an account if you don't yet have one.

You must have cookies enabled in your web browser to be able to login.

Username
Password

Forgotten your password? Get a new one here.