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Hydrothermal formation of magnetic Ni–Cu alloy nanocrystallites at low temperatures

H L Niu, Q W Chen1, Y S Lin, Y S Jia, H F Zhu and M Ning

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Magnetic Ni–Cu alloy nanocrystallites with a diameter of about 12 nm have been prepared by a hydrothermal approach with polymer–surfactant complex association at 80 °C. XRD, TEM and ICP-AES were employed to characterize alloy nanocrystallites. The magnetic properties of alloy nanocrystallites were measured using a vibrating sample magnetometer (VSM). The influences of polymer–micelle association, temperature and concentration of micelles on the formation of alloy are discussed. Polymer–micelle association provides a way for Ni and Cu to be reduced simultaneously and then occupy the Cu lattice to form Ni–Cu alloy nanocrystallites.


PACS

81.07.Bc Nanocrystalline materials

75.75.+a Magnetic properties of nanostructures

68.47.Mn Polymer surfaces

68.37.Lp Transmission electron microscopy (TEM)

82.30.Nr Association, addition, insertion, cluster formation

61.05.cp X-ray diffraction

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 8 (August 2004)

Received 24 March 2004

Published 21 June 2004



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