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The high-bias stability of monatomic chains

R H M Smit1, C Untiedt2 and J M van Ruitenbeek1

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For the metals Au, Pt and Ir it is possible to form freely suspended monatomic chains between bulk electrodes. The atomic chains sustain very large current densities, but finally fail at high bias. We investigate the breaking mechanism, that involves current-induced heating of the atomic wires and electromigration forces. We find good agreement of the observations for Au based on models due to Todorov and co-workers. The high-bias breaking of atomic chains for Pt can also be described by the models, although here the parameters have not been obtained independently. In the limit of long chains the breaking voltage decreases inversely proportional to the length.


PACS

65.80.+n Thermal properties of small particles, nanocrystals, nanotubes

63.22.-m Phonons or vibrational states in low-dimensional structures and nanoscale materials

84.37.+q Electric variable measurements (including voltage, current, resistance, capacitance, inductance, impedance, and admittance, etc.)

Subjects

Electronics and devices

Instrumentation and measurement

Nanoscale science and low-D systems

Dates

Issue 7 (July 2004)

Received 19 November 2003

Published 17 May 2004



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