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The effect of ionization on cluster formation in laser ablation plumes

M S Tillack, D W Blair and S S Harilal

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Ablation plumes caused by short-pulse laser irradiation provide conditions which are well suited to the formation of nanoclusters. The high saturation ratios and presence of ionization lead to extraordinarily high nucleation rates and small critical radii. We have explored the homogeneous nucleation and heterogeneous growth of condensates from Si targets expanding into a low-pressure He ambient using a Nd:YAG laser with a pulse length of 8 ns, wavelength of 532 nm and intensities in the range of 5 × 107–5 × 109 W cm−2. Clusters in the range of 5–50 nm have been produced. In the highly dynamic, non-linear regime of short-pulse laser–matter interactions, plume evolution and condensation processes are strongly coupled and difficult to predict accurately from modelling alone. Both numerical predictions and experimental results were used to quantify the competing effects of ionization and supersaturation. The results suggest a dominant influence of ionization for nearly all intensities above the ablation threshold.


PACS

61.80.Ba Ultraviolet, visible, and infrared radiation effects (including laser radiation)

52.70.Kz Optical (ultraviolet, visible, infrared) measurements

51.70.+f Optical and dielectric properties

52.38.Mf Laser ablation

42.60.Jf Beam characteristics: profile, intensity, and power; spatial pattern formation

Subjects

Instrumentation and measurement

Optics, quantum optics and lasers

Plasma physics

Condensed matter: structural, mechanical & thermal

Dates

Issue 3 (March 2004)

Received 23 August 2003, in final form 13 November 2003

Published 21 January 2004



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