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Transport in single-molecule transistors: Kondo physics and negative differential resistance

Lam H Yu and Douglas Natelson

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We report two examples of transport phenomena based on sharp features in the effective density of states of molecular-scale transistors: Kondo physics in C60-based devices, and gate-modulated negative differential resistance (NDR) in 'control' devices that we ascribe to adsorbed contamination. We discuss the need for a statistical approach to device characterization, and the criteria that must be satisfied to infer that transport is based on single molecules. We describe apparent Kondo physics in C60-based single-molecule transistors (SMTs), including signatures of molecular vibrations in the Kondo regime. Finally, we report gate-modulated NDR in devices made without intentional molecular components, and discuss possible origins of this property.


PACS

72.10.Fk Scattering by point defects, dislocations, surfaces, and other imperfections (including Kondo effect)

85.65.+h Molecular electronic devices

Subjects

Electronics and devices

Condensed matter: electrical, magnetic and optical

Dates

Issue 10 (October 2004)

Received 26 January 2004

Published 23 July 2004



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