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Nanostructure fabrication using block copolymers

REVIEW ARTICLE

I W Hamley

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TOPICAL REVIEW

A brief overview is provided of recent developments in the use of block copolymer self-assembly to create morphologies that may be used to template the fabrication of nanostructures in other materials. The patterning of semiconductor surfaces using block copolymer film masks and the production of high-density arrays of magnetic domains are discussed. The use of block copolymer micelles as 'nanoreactors' to prepare metal and semiconductor nanoparticles is considered, and methods to pattern nanoparticles are highlighted. A number of approaches to design nanocapsules are summarized. Finally, applications of bulk nanostructures to make mesoporous materials with controlled pore structures and sizes, or to create photonic crystals, are discussed.


PACS

81.16.Dn Self-assembly

61.41.+e Polymers, elastomers, and plastics

68.47.Fg Semiconductor surfaces

61.46.-w Structure of nanoscale materials

81.16.Rf Nanoscale pattern formation

81.07.Bc Nanocrystalline materials

Subjects

Soft matter, liquids and polymers

Semiconductors

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 10 (October 2003)

Received 4 July 2003, in final form 29 July 2003

Published 17 September 2003



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