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Effect of acetylene in buffer gas on the microstructures of carbon nanotubes in arc discharge

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D S Tang, S S Xie, B H Chang, L F Sun, Z Q Liu, X P Zou, Y B Li, L J Ci, W Liu, W Y Zhou and G Wang

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LETTER TO THE EDITOR

We have investigated the changes in the morphology and microstructure of carbon nanotubes (CNTs) brought about by acetylene in the buffer gas of helium in arc discharge. Observations using scanning electron microscopy and transmission electron microscopy indicate that, with the introduction of acetylene, on the one hand, the diameters of spots in the central pattern region decrease markedly and CNTs are embellished with nanoparticles on the top surface of cathode deposit; and, on the other hand, the outer and inner diameters of CNTs decrease evidently. These results indicate that the outer diameter and innermost empty space of the nanotubes are related to growth conditions such as the density of carbon species and temperature in the growth region. This suggests that the outer and inner diameters of CNTs are adjustable by controlling the growth conditions in the growth region.


PACS

52.80.Mg Arcs; sparks; lightning; atmospheric electricity

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

68.37.Lp Transmission electron microscopy (TEM)

61.46.-w Structure of nanoscale materials

Subjects

Surfaces, interfaces and thin films

Plasma physics

Nanoscale science and low-D systems

Dates

Issue 4 (August 2002)

Received 11 January 2002, in final form 29 May 2002

Published 21 June 2002



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