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A study of the self-aligned nanometre scale palladium clusters on silicon formation process

S Gavrilov-+, S Lemeshko-+, V Shevyakov-+ and V Roschin++

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The possibility of the self-aligned formation of Pd/Pd2Si/Si nanostructures on a single-crystal silicon substrate is shown. A porous anodic oxide film of Al was used as a mask which determines the size and shape of the nanostructures. A thin Al film was first deposited on the silicon substrate and then transformed in a nanoporous oxide by the well known anodic treatment procedure in a sulfuric acid and water solution. It is shown by atomic force microscopy that nanoscale Pd clusters with diameters equal to the size of pores in anodic Al remain at the surface of silicon substrate after cathode deposition of Pd into the pores, vacuum thermal annealing and chemical etching of the Al2O3 mask. In addition, we determine the dependencies of the size and shape of the nanoclusters on the mask formation regimes and the Pd deposition conditions.


PACS

61.46.-w Structure of nanoscale materials

68.37.Ps Atomic force microscopy (AFM)

81.65.Cf Surface cleaning, etching, patterning

81.40.Gh Other heat and thermomechanical treatments

81.16.Nd Nanolithography

Subjects

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 2 (June 1999)

Received 27 October 1998



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