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A thermoelectric scanning facility for the study of elemental thermocouples

Robin E Bentley

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A scanning facility for studying the thermoelectric behaviour of the metals used in elemental thermocouples (Au, Pt and Pd) is described. The facility effectively measured changes in Seebeck coefficient along a 560 mm length of each of three wires, relative to a fourth, by moving them through a 50 mm long, EMF-producing zone into a uniform-temperature region at 250 °C. The uniform region was stable to within 0.7 mK and EMF measurements were made to 10 nV (equivalent to about 1 mK). Accordingly, the facility is able to detect changes of ~10 ppm in Seebeck coefficient. The precautions necessary to work at this accuracy are detailed and preliminary data on the changes that occur at temperatures up to 1000 °C are reported. For example, the measured Seebeck coefficient of Pd decreased at temperatures in the range 550 to 850 °C, a change opposite in sign to that previously reported.


PACS

07.20.Dt Thermometers

06.20.F- Units and standards

72.15.Jf Thermoelectric and thermomagnetic effects

Subjects

Condensed matter: electrical, magnetic and optical

Instrumentation and measurement

Dates

Issue 5 (May 2000)

Received 19 January 2000, accepted for publication 10 March 2000, in final form 10 March 2000



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