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A technique for in situ measurement of the conductivity of water in `triple point of water' cells

Mark Ballico

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Sealed glass ampoules made for the realization of the triple point of water as a thermometric reference point, 0.01 °C, must be filled with water of the highest possible purity. This paper discusses a simple electrical technique for measurement of the conductivity of high-purity water within such cells, and presents calculations of the calibration factor in this geometry. The technique is then applied to a large set of cells, some dating back up to 40 years, and the results are compared with measurements of the cells' triple point temperature. The measurements indicate that the effective ionic conductivity of the impurities in the cells is as low as 2 mS m2 mol-1.


PACS

84.37.+q Electric variable measurements (including voltage, current, resistance, capacitance, inductance, impedance, and admittance, etc.)

07.20.Dt Thermometers

06.20.F- Units and standards

66.10.Ed Ionic conduction

Subjects

Soft matter, liquids and polymers

Electronics and devices

Instrumentation and measurement

Dates

Issue 7 (July 1999)

Received 15 April 1999, accepted for publication 2 June 1999, in final form 24 May 1999



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