L Léger et al 1997 J. Phys.: Condens. Matter 9 7719 doi:10.1088/0953-8984/9/37/006
L Léger, H Hervet, G Massey and E Durliat
Show affiliationsWe present a review of the recent characterizations of the flow behaviour of high-molecular-weight polymer melts, with special emphasis on situations in which slip at the wall appears. These characterizations are based on direct measurements of the local velocity of the fluid, in the immediate vicinity of the solid wall, through near-field velocimetry techniques. The results demonstrate the importance of polymer molecules anchored on the solid surface, either by strong adsorption or by chemical grafting, and entangled with the bulk polymer, to produce a strong friction at low shear rates and to lead to a shear rate threshold above which strong slip at the wall and low friction develop. The evolution of the shear rate threshold and of the flow characteristics (the length of the extrapolation of the velocity profile to zero, the critical slip velocity for the onset of strong slip, ...) with the molecular parameters of the system (the molecular weights of the bulk and surface chains, and the surface density of anchored chains) is analysed and compared with the predictions of recent theoretical models.
61.25.H- Macromolecular and polymers solutions; polymer melts
62.10.+s Mechanical properties of liquids
68.47.Pe Langmuir-Blodgett films on solids; polymers on surfaces; biological molecules on surfaces
Issue 37 (15 September 1997)
Received 25 February 1997
L Léger et al 1997 J. Phys.: Condens. Matter 9 7719
Xian Gao et al JCAP11(2009)007
Lorenzo J Díaz and Bianca Santoro 2004 Nonlinearity 17 1001
V M Castillo-Vallejo et al 2006 J. Phys.: Conf. Ser. 37 5
H Vocca et al 2004 Class. Quantum Grav. 21 S665
P Dale 2004 J. Phys. A: Math. Gen. 37 2299
P de Villiers et al 1992 J. Phys.: Condens. Matter 4 9401
Eli Rotenberg et al 2005 New J. Phys. 7 114
Aiyalam P. Balachandran et al JHEP10(2004)072
D R Bates 1983 J. Phys. B: At. Mol. Phys. 16 L295