Quick search Find article
Quick search
Find article

Wall slip in polymer melts

L Léger, H Hervet, G Massey and E Durliat

Show affiliations


We present a review of the recent characterizations of the flow behaviour of high-molecular-weight polymer melts, with special emphasis on situations in which slip at the wall appears. These characterizations are based on direct measurements of the local velocity of the fluid, in the immediate vicinity of the solid wall, through near-field velocimetry techniques. The results demonstrate the importance of polymer molecules anchored on the solid surface, either by strong adsorption or by chemical grafting, and entangled with the bulk polymer, to produce a strong friction at low shear rates and to lead to a shear rate threshold above which strong slip at the wall and low friction develop. The evolution of the shear rate threshold and of the flow characteristics (the length of the extrapolation of the velocity profile to zero, the critical slip velocity for the onset of strong slip, ...) with the molecular parameters of the system (the molecular weights of the bulk and surface chains, and the surface density of anchored chains) is analysed and compared with the predictions of recent theoretical models.


PACS

61.25.H- Macromolecular and polymers solutions; polymer melts

68.43.Mn Adsorption kinetics

62.10.+s Mechanical properties of liquids

68.47.Pe Langmuir-Blodgett films on solids; polymers on surfaces; biological molecules on surfaces

Subjects

Soft matter, liquids and polymers

Surfaces, interfaces and thin films

Dates

Issue 37 (15 September 1997)

Received 25 February 1997



  1. Wall slip in polymer melts

    L Léger et al 1997 J. Phys.: Condens. Matter 9 7719

  2. Primordial non-Gaussianities from the trispectra in multiple field inflationary models

    Xian Gao et al JCAP11(2009)007

  3. Collision, explosion and collapse of homoclinic classes

    Lorenzo J Díaz and Bianca Santoro 2004 Nonlinearity 17 1001

  4. Λ0 polarization as function of target density

    V M Castillo-Vallejo et al 2006 J. Phys.: Conf. Ser. 37 5

  5. Simulation of the charging process of the LISA test masses due to solar flares

    H Vocca et al 2004 Class. Quantum Grav. 21 S665

  6. The Kramer–Neugebauer limit and Nakamura's conjecture

    P Dale 2004 J. Phys. A: Math. Gen. 37 2299

  7. Superconducting fluctuations in the thermoelectric power and resistivity of Bi-based polycrystalline cuprates

    P de Villiers et al 1992 J. Phys.: Condens. Matter 4 9401

  8. Electron states and the spin density wave phase diagram in Cr(1 1 0) films

    Eli Rotenberg et al 2005 New J. Phys. 7 114

  9. Unitary quantum physics with time-space noncommutativity

    Aiyalam P. Balachandran et al JHEP10(2004)072

  10. Termolecular ionic recombination at high ambient gas density

    D R Bates 1983 J. Phys. B: At. Mol. Phys. 16 L295

Users also read

What's this?
This innovative new feature generates a list of articles 'also read' by other users based on them reading the original article. Article abstracts citations and references are all considered and weighted accordingly. We hope that this will help you find relevant papers for your research.

  1. Boundary slip in Newtonian liquids: a review of experimental studies

Related review articles

What's this?
View review articles related to this research to gain an insight into the key trends in this subject area. Related review articles are selected based on PACS/MSC codes, and are no more than three years old.

  1. Systematic coarse-graining of the dynamics of entangled polymer melts: the road from chemistry to rheology
  2. Liquid water and ices: understanding the structure and physical properties

View by subject




Export








Please login to access our web services, or create an account if you don't yet have one.

You must have cookies enabled in your web browser to be able to login.

Username
Password

Forgotten your password? Get a new one here.