A B Kuz'menko et al 1996 J. Phys.: Condens. Matter 8 6199 doi:10.1088/0953-8984/8/34/010
A B Kuz'menko
, E A Tishchenko
and V G Orlov![]()
Measurements of infrared polarized reflectance spectra of single-crystal
have been made at room temperature in the wavelength range from 30 to
for different orientations of the wave vector k and the electric field E of the incident radiation relative to the crystallographic axes. On the basis of Born and Huang's theory, relations between characteristics of TO modes of the monoclinic lattice and the reflectivity for the orientations used are established. Dipole momentum orientations, frequencies, strengths and linewidths of almost all of the IR-active modes predicted by the factor-group analysis for the
were determined. Good agreement between experimentally measured and model spectra was achieved. It was shown that in order to obtain reliable values of parameters of
modes three spectra for different orientations of E in the ac-plane should be fitted simultaneously. It was found that
modes have significantly greater intensities than
modes. The effect of the rotation of the principal dielectric axes within the ac-plane was studied.
78.30.Hv Other nonmetallic inorganics
61.50.Ah Theory of crystal structure, crystal symmetry; calculations and modeling
Issue 34 (19 August 1996)
Received 7 May 1996
A B Kuz'menko et al 1996 J. Phys.: Condens. Matter 8 6199
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