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The temperature dependence of resistivity and thermoelectric power in lanthanum molybdenum oxide crystal

Tian Mingliang, Mao Zhiqiang and Zhang Yuheng

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Electrical resistivity, voltage - current (V - I) characteristics and thermoelectric power (TEP) at various temperatures in the quasi-two-dimensional single crystal were measured. It was found that at 130 K the resistivity shows a metal - semiconductor transition, and the TEP has a minimum value. In the semiconducting states below 130 K, the electronic transport presents a clear non-linear behaviour. By analysis of the above data, it is indicated that above 130 K the crystal is a metal and electrons are dominant carriers; below 130 K the crystal becomes a semiconductor with a small energy gap, the two types of carrier being possibly co-existent. The anomalies of TEP and resistivity near 130 K may be associated with the formation of so-called charge-density waves due to the partial opening of a gap.


PACS

72.20.Pa Thermoelectric and thermomagnetic effects

71.45.Lr Charge-density-wave systems

71.20.Ps Other inorganic compounds

71.30.+h Metal-insulator transitions and other electronic transitions

72.80.Sk Insulators

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Dates

Issue 19 (6 May 1996)

Received 19 December 1995, in final form 5 February 1996



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